The Modification of Useful Injection-Molded Parts' Properties Induced Using High-Energy Radiation.

The modification of polymer materials' useful properties can be applicable in many industrial areas due to the ability to make commodity and technical plastics (plastics that offer many benefits, such as processability, by injection molding) useful in more demanding applications. In the case of injection-molded parts, one of the most suitable methods for modification appears to be high-energy irradiation, which is currently used primarily for the modification of mechanical and thermal properties. However, well-chosen doses can effectively modify the properties of the surface layer as well. The purpose of this study is to provide a complex description of high-energy radiation's (ß radiation) influence on the useful properties of injection-molded parts made from common polymers. The results indicate that ß radiation initiates the cross-linking process in material and leads to improved mechanical properties. Besides the cross-linking process, the material also experiences oxidation, which influences the properties of the surface layer. Based on the measured results, the main outputs of this study are appropriately designed regression models that determine the optimal dose of radiation.

Dynamic Behavior of Thermally Affected Injection-Molded High-Density Polyethylene Parts Modified by Accelerated Electrons.

Polyethylenes are the most widely used polymers and are gaining more and more interest due to their easy processability, relatively good mechanical properties and excellent chemical resistance. The disadvantage is their low temperature stability, which excludes particular high-density polyethylenes (HDPEs) for use in engineering applications where the temperature exceeds 100 °C for a long time. One of the possibilities of improving the temperature stability of HDPE is a modification by accelerated electrons when HDPE is cross-linked by this process and it is no longer possible to process it like a classic thermoplastic, e.g., by injection technology. The HDPE modified in this way was thermally stressed five times at temperatures of 110 and 160 °C, and then the dynamic tensile behavior was determined. The deformation and surface temperature of the specimens were recorded by a high-speed infrared camera. Furthermore, two thermal methods of specimen evaluation were used: differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The result of the measurement is that the modification of HDPE by accelerated electrons had a positive effect on the dynamic tensile behavior of these materials.

Effect of Temperature Ageing on Injection Molded High-Density Polyethylene Parts Modified by Accelerated Electrons.

The temperature ageing of high-density polyethylene (HDPE) modified by accelerated electrons was studied. Commodity plastic HDPE was used as a basic polymer material which was modified by radiation cross-linking. This polymer was used because of its excellent processability and chemical resistance. Plastic injection molding technology was used for the production of test specimens. These specimens were modified with the dose of radiation 33, 66, 99, 132, 165, and 198 kGy. The prepared specimens were tested to determine: gel content, degree of swelling, temperature stability, and changes in mechanical properties after temperature ageing. The results were determined by scanning electron microscopy (SEM) analysis on the fracture surfaces. The results of this study confirm that modification of HDPE by radiation cross-linking has a significant effect on increasing temperature stability. It has been shown that HDPE modified by radiation cross-linking can withstand temperatures exceeding the melting point of the original HDPE for a short-term.

Influence of the ß- Radiation/Cold Atmospheric-Pressure Plasma Surface Modification on the Adhesive Bonding of Polyolefins.

The goal of this research was to examine the effect of two surface modification methods, i.e., radiation cross-linking and plasma treatment, on the adhesive properties and the final quality of adhesive bonds of polypropylene (PP), which was chosen as the representative of the polyolefin group. Polymer cross-linking was induced by beta (accelerated electrons-ß-) radiation in the following dosages: 33, 66, and 99 kGy. In order to determine the usability of ß- radiation for these applications (improving the adhesive properties and adhesiveness of surface layers), the obtained results were compared with values measured on surfaces treated by cold atmospheric-pressure plasma with outputs 2.4, 4, and 8 W. The effects of both methods were compared by several parameters, namely wetting contact angles, free surface energy, and overall strength of adhesive bonds. Furthermore, Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) were conducted. According to our findings the following conclusion was reached; both tested surface modification methods significantly altered the properties of the specimen's surface layer, which led to improved wetting, free surface energy, and bond adhesion. Following the ß- radiation, the free surface energy of PP rose by 80%, while the strength of the bond grew in some cases by 290% in comparison with the non-treated surface. These results show that when compared with cold plasma treatment the beta radiation appears to be an effective tool capable of improving the adhesive properties and adhesiveness of PP surface layers.

Polyamide Surface Layer Nano-Indentation and Thermal Properties Modified by Irradiation.

This study describes the effect of electron radiation on the nano-mechanical properties of surface layers of selected polyamide (PA) types. Electron radiation initiates the cross-linking of macromolecules in the polyamide structure, leading to the creation of a 3D network which fundamentally changes the properties of the tested polymers. Selected types of polyamide (PA 6, PA 66 and PA 9T) were exposed to various intensities of electron radiation (33 kGy, 66 kGy, 99 kGy, 132 kGy, 165 kGy and 198 kGy). The cross-linked polyamides' surface properties were measured by means of the modern nano-indentation technique (Depth Sensing Indentation; DSI), which operates on the principle of the immediate detection of indenter penetration depth in dependence on the applied load. The evaluation was preformed using the Oliver-Pharr method. The effect of electron radiation on the tested polyamides manifested itself in the creation of a 3D network, which led to an increase of surface layer properties, such as indentation hardness, elastic modulus, creep and temperature resistance, by up to 93%. The increase of temperature and mechanical properties substantially broadens the field of application of these materials in technical practice, especially when higher temperature resistance is required. The positive changes to the nano-mechanical properties as well as mechanical and temperature capabilities instigated by the cross-linking process were confirmed by the gel volume test. These measurements lay the foundation for a detailed study of this topic, as well as for a more effective means of modifying chosen properties of technical polyamide products by radiation.

Nano-Mechanical Properties of Surface Layers of Polyethylene Modified by Irradiation.

This study's goal was to describe the influence of a wide range of ionizing beta radiation upon the changes in surface layer mechanical properties and structural modifications of selected types of polymer. Radiation crosslinking is a process whereby the impingement of high-energy electrons adjusts test sample structures, thus enhancing the useful properties of the material, e.g., hardness, wear-resistance, and creep, in order that they may function properly during their technical use. The selected polymers tested were polyolefin polymers like polyethylene (Low-density polyethylene LDPE, High-density polyethylene HDPE). These samples underwent exposure to electron radiation of differing dosages (33, 66, 99, 132, 165, and 198 kGy). After the crosslinking process, the samples underwent testing of the nano-mechanical properties of their surface layers. This was done by means of a state-of-the-art indentation technique, i.e., depth-sensing indentation (DSI), which detects the immediate change in the indentation depth associated with the applied force. Indeed, the results indicated that the optimal radiation dosage increased the mechanical properties by up to 57%; however, the beneficial levels of radiation varied with each material. Furthermore, these modifications faced examination from the structural perspective. For this purpose, a gel test, Raman spectroscopy, and crystalline portion determination by X-ray all confirmed the assumed trends.

Effect of Beta Radiation on the Quality of the Bonded Joint for Difficult to Bond Polyolefins.

Bonding is increasingly being used, and it is an ever-evolving method for creating unbreakable bonds. The strength of adhesive bonds determines, to a significant extent, the possible applications of this technology and is influenced by many factors. In addition to the type of adhesive used, the characteristics of the surface layers play a significant role; therefore, significant attention is paid to their adjustment and modification. Radiation crosslinking is one of the most important methods for modifying polymer properties. Currently, the most frequently used type of radiation for polymer crosslinking is beta minus (ß-) radiation, which affects not only mechanical but also surface properties, chemical and temperature resistance, and surface layer characteristics of polymers. This study investigated the effect of ß- radiation on the surface layer properties of low-density polyethylene (LDPE), high-density polyethylene (HDPE), and polypropylene (PP) and the effects of surface-layer modification on the ultimate tensile strength of bonded joints. Based on the results, we concluded that ß- radiation significantly changes the properties of the tested surface layers, increases the surface energy, and improves the adhesiveness of bonds. Consequently, the final strength of the LDPE, HDPE, and PP bonds increases significantly.

The High Density Polyethylene Composite with Recycled Radiation Cross-Linked Filler of rHDPEx.

This article discusses the possibilities of using radiation cross-linked high density polyethylene (HDPEx) acting as a filler in the original high density polyethylene (HDPE) matrix. The newly created composite is one of the possible answers to questions relating to the processing of radiation cross-linked thermoplastics. Radiation cross-linked networking is-nowadays, a commonly used technology that can significantly modify the properties of many types of thermoplastics. This paper describes the influence of the concentration of filler, in the form of grit or powder obtained by the grinding/milling of products/industrial waste from radiation cross-linked high density polyethylene (rHDPEx) on the mechanical and processing properties and the composite structure. It was determined that, by varying the concentration of the filler, it is possible to influence the mechanical behaviour of the composite. The mechanical properties of the new composite-measured at room temperature, are generally comparable or better than the same properties of the original thermoplastic. This creates very good assumptions for the effective and economically acceptable, processing of high density polyethylene (rHDPEx) waste. Its processability however, is limited; it can be processed by injection moulding up to 60 wt %.

Mechanical Properties Changes of Irradiated Thermoplastic Elastomer.

Some polymers need a cross-linking agent for the controlled cross-linking process of polymers with a tendency to degradation during the radiation cross-linking process. While, on the other hand, other polymers do not need a cross-linking agent-predominantly there are cross-linking polymers. The Thermo-Plastic Elastomer (TPE) that was used belongs to this group of predominantly cross-linking polymers; however, this agent is added because of faster reaction times and smaller irradiation doses. Microindentation⁻tensile and tensile impact tests were carried out on a thermoplastic sample-with, and without, a cross-linking agent. Small changes were measured between these materials at low radiation doses, (up to 66 kGy); nevertheless, at higher doses, the influence of the cross-linking agent on the mechanical properties is significant.

The Effect of Irradiation on Mechanical and Thermal Properties of Selected Types of Polymers.

This article deals with the influence of electron-beam radiation on the micro-mechanical, thermo-mechanical, and structural properties of selected polymers. In the search for the desired improvement of polymers, it is possible to use, inter alia, one particular possible modification-Namely, crosslinking-Which is a process during which macromolecular chains start to connect to each other and, thus, create the spatial network in the structure. In the course of the treatment of the ionizing radiation, two actions can occur: crosslinking and scission of macromolecules, or degradation. Both these processes run in parallel. Using the crosslinking technology, standard and technical polymers can acquire the more "expensive" high-tech polymeric material properties and, thus, replace these materials in many applications. The polymers that were tested were selected from across the whole spectra of thermoplastics, ranging from commodity polymers, technical polymers, as well as high-performance polymers. These polymers were irradiated by different doses of beta radiation (33, 66, 99, 132, 165, and 198 kGy). The micro-mechanical and thermo-mechanical properties of these polymers were measured. When considering the results, it is obvious that irradiation acts on each polymer differently but, always when the optimal dose was found, the mechanical properties increased by up to 36%. The changes of micro-mechanical and thermo-mechanical properties were confirmed by structural measurement when the change of the micro-hardness and modulus corresponded to the crystalline phase change as determined by X-ray and gel content.

The Electrical, Mechanical and Surface Properties of Thermoplastic Polyester Elastomer Modified by Electron Beta Radiation.

The main advantages of Thermoplastic Polyester Elastomers (TPE-E) are their elastomer properties as well as their ability to be processed in the same way as thermoplastic polymers (e.g., injection moulding, compression moulding and extrusion). However, TPE-Es' properties, mainly their mechanical properties and thermal characteristics, are not as good as those of elastomers. Because of this TPE-Es are often modified with the aim of improving their properties and extending their range of application. Radiation cross-linking using accelerated electron beams is one of the most effective ways to change virgin polymers' properties significantly. Their electrical (that is to say permittivity and resistivity measurements), mechanical (that is, tensile and impact tensile tests), as well as surface (that is, nano-indentation) properties were measured on modified/cross-linked TPE-E specimens with and/or without a cross-linking agent at irradiation doses of 0, 33, 66, 99, 132, 165 and 198 kGy. The data acquired from these procedures show significant changes in the measured properties. The results of this study allow the possibility of determining the proper processing parameters and irradiation doses for the production of TPE-E products which leads to the enlargement of their application in practice.

Use of Irradiated Polymers after Their Lifetime Period.

This article deals with the study of the utilisation of irradiated HDPE products after their end-of-life cycle. Today, polymer waste processing is a matter of evermore intensive discussion. Common thermoplastic waste recycling-especially in the case of wastes with a defined composition-is generally well-known-and frequently used. On the contrary, processing cross-linked plastics is impossible to do in the same way as with virgin thermoplastics-mainly due to the impossibility of remelting them. The possibility of using waste in the form of grit or a powder, made from cross-linked High Density PolyEthylene (rHDPEx) products, after their end-of-life cycle, as a filler for virgin Low Density PolyEthylene (LDPE) was tested in a matrix. It was found that both the mechanical behaviour and processability of new composites with an LDPE matrix, with rHDPEx as a filler, depend-to a high degree-on the amount of the filler. The composite can be processed up to 60% of the filler content. The Polymer Mixture Fluidity dropped significantly, in line with the amount of filler, while the mechanical properties, on the other hand, predominantly grew with the increasing amount of rHDPEx.